Reactions of halides with trans-[Re(CO)4(MeCN)(NS)][AsF6]2: syntheses and structure of trans-[Re(CO)4(Cl)(NS)][AsF6] and [(OC)5ReNS–NS–N[Re(CO)5]S{N–SNRe(CO)5}–CH2–CH2][AsF6]2, an unusual trinuclear bis(thiazyl)rhenium complex
Abstract
From the reactions of trans-[Re(CO)4(MeCN)(NS)][AsF6]2 with CsCl, trans-[Re(CO)4(Cl)(NS)][AsF6].MeCN 2 is formed, and with CsF [{Re(CO)5}3(C2H2N5S4)] 3 is isolated; the X-ray crystal structure of 2 and 3 are reported.