A new carbon–carbon bond forming reaction using O-methyl (S)-prop-2-ynyl dithiocarbonate
Abstract
Heating O-methyl (S)- prop-2-ynyl dithiocarbonate 1a–c with electrophilic alkenes 7a–d containing nucleophilic acetoxy group gives 1,3-dithiol-2-ones 9 by a new carbon–carbon bond forming process.