SCHEDULED MAINTENANCE
The palladium catalysed reactions of pronucleophiles 1 with allenylstannanes 2 or prop-2-ynylstannanes 3 give the corresponding addition–substitution products 4 in reasonable to high yields; this double alkylation reaction most probably proceeds through an allylstannane intermediate.
Y. Yamamoto, M. Al-Masum and N. Fujiwara, Chem. Commun., 1996, 381 DOI: 10.1039/CC9960000381
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