Aldimines are transformed into homoallylic amines by treatment with allylic barium reagents in which both the α- and γ-adducts are selectively obtained by simply changing the reaction temperature.
A. Yanagisawa, K. Ogasawara, K. Yasue and H. Yamamoto, Chem. Commun., 1996, 367 DOI: 10.1039/CC9960000367
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