The ambiphilic nature of β-keto esters and β-diketones allows cycloaddition to C60 in the presence of piperidine to give dihydrofuran-fused C60 derivatives via oxidative cyclization complimentary to the concerted process.
M. Ohno, A. Yashiro and S. Eguchi, Chem. Commun., 1996, 291 DOI: 10.1039/CC9960000291
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