Issue 3, 1996

Base-catalysed oxidative [3 + 2]cycloaddition reaction of [60]fullerene with β-dicarbonyl compounds

Abstract

The ambiphilic nature of β-keto esters and β-diketones allows cycloaddition to C60 in the presence of piperidine to give dihydrofuran-fused C60 derivatives via oxidative cyclization complimentary to the concerted process.

Article information

Article type
Paper

Chem. Commun., 1996, 291-292

Base-catalysed oxidative [3 + 2]cycloaddition reaction of [60]fullerene with β-dicarbonyl compounds

M. Ohno, A. Yashiro and S. Eguchi, Chem. Commun., 1996, 291 DOI: 10.1039/CC9960000291

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