The titanium silicate molecular sieve, TS-1, efficiently catalyses the formation of carbon–carbon bond in the Mukaiyama type aldol reaction of silyl enol ethers and aldehydes forming β-hydroxy esters/aldols in high yields under heterogeneous and ambient reaction conditions.
M. Sasidharan, S. V. N. Raju, K. V. Srinivasan, V. Paul and R. Kumar, Chem. Commun., 1996, 129 DOI: 10.1039/CC9960000129
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