Trifluorovinyllithium has been synthesised in high yield from 1,1,1,2-tetrafluoroethane (HFC 134a) by treatment with butyllithium at –78 °C, and then treated with a variety of electrophiles in one-pot reactions.
J. Burdon, P. L. Coe, I. B. Haslock and R. L. Powell, Chem. Commun., 1996, 49 DOI: 10.1039/CC9960000049
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