Unprecedentedly stable (µ-η6:η6-pentafulvadiene) diruthenium complexes are obtained upon 2e-oxidation of 1,2-bis(ruthenocenyl)ethylenes, prepared from the reaction of ruthenocenylaldehydes with low-valent titanium.
M. Sato, A. Kudo, Y. Kawata and H. Saitoh, Chem. Commun., 1996, 25 DOI: 10.1039/CC9960000025
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