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Issue 22, 1996
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Synthesis, photophysics and photochemistry of alkynylgold(I) phosphine complexes

Abstract

A series of alkynylgold(I) phosphine complexes with various bridging phosphines and acetylide ligands have been synthesized. All complexes have been shown to exhibit rich photophysical and photochemical behaviour. A systematic comparative study on their spectroscopy and photophysics has been attempted. The complexes undergo facile electron-transfer reactions with pyridinium electron acceptors. The redox nature of the quenching reactions has been established by time-resolved transient absorption spectroscopy.

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J. Chem. Soc., Dalton Trans., 1996, 4227-4232
Article type
Paper

Synthesis, photophysics and photochemistry of alkynylgold(I) phosphine complexes

V. W. Yam and S. W. Choi, J. Chem. Soc., Dalton Trans., 1996, 4227 DOI: 10.1039/DT9960004227

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