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Issue 18, 1996
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First determination of the rate acceleration of a palladium-catalysed coupling reaction by use of high pressure

Abstract

The activation volume, ΔV, reflecting the rate acceleration by pressure, of the coupling reaction between 2,3-dihydrofuran and iodobenzene is determined as –12 ± 2 cm–3 by kinetic measurements at pressures between 1 bar and 8 kbar; moreover, our kinetic data suggest that the rate-determining step is not the oxidative addition of iodobenzene to the palladium catalyst.

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Article information


Chem. Commun., 1996, 2197-2198
Article type
Paper

First determination of the rate acceleration of a palladium-catalysed coupling reaction by use of high pressure

S. Hillers and O. Reiser, Chem. Commun., 1996, 2197
DOI: 10.1039/CC9960002197

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