Nanostructured Pd clusters, prepared either electrochemically using a sacrificial Pd anode or by thermolysis of Pd(O2CMe)2, are stable in propylene carbonate even at 140–155 °C; such colloidal solutions catalyse Heck reactions in the absence of phosphine ligands.
M. T. Reetz and G. Lohmer, Chem. Commun., 1996, 1921 DOI: 10.1039/CC9960001921
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