Dimeric homochiral ruthenium complexes [L2Ru{dppz(11-11′)ddpz}RuL2]4+(L = 1,10-phenanthroline, 2,2′-bipyridyl; dppz = dipyrido[3,2-A: 2′,3′-C]phenazine) bind extremely strongly to duplex DNA with different binding geometries for the ΔΔ and ΔΔ enantiomers of the phenanthroline complex but with similar geometries for the bipyridyl complex enantiomers.
P. Lincoln and B. Nordén, Chem. Commun., 1996, 2145 DOI: 10.1039/CC9960002145
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