Issue 14, 1996
From the journal:

Chemical Communications

Switchable photoreduction pathways of antimony(V) tetraphenylporphyrin. A potential multielectron transfer photosensitizer

Günther Knör,   Arnd Vogler,   Sergio Roffia,   Francesco Paolucci  and  Vincenzo Balzani  

Abstract

Photoreduction of [SbV(tpp)(OH)2]+(tpp = dianion of 5,10,15,20-tetraphenylporphyrin) yields either the metastable π-radical anion [SbV(tpp˙–)(OH)2] or the two-electron reduced[SbIII(tpp)]+ complex; product formation can be channelled in the desired direction by an appropriate choice of the reaction medium and dioxygen regenerates the starting compound.

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Article information

DOI
https://doi.org/10.1039/CC9960001643
Article type
Paper

Chem. Commun., 1996, 1643-1644

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Switchable photoreduction pathways of antimony(V) tetraphenylporphyrin. A potential multielectron transfer photosensitizer

G. Knör, A. Vogler, S. Roffia, F. Paolucci and V. Balzani, Chem. Commun., 1996, 1643 DOI: 10.1039/CC9960001643

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