The rates of the acid-catalysed hydrolysis of diethyl 2-pyridyl phosphate and of the base-promoted hydrolysis of N-methyl-8-(dimethylphosphoryloxy)quinolinium ion have been determined in the presence of different cations as buffer components. For both substrates the rate depends on the nature of the cations, indicating the participation of a substrate–cation complex in the reaction.
M. Mentz and T. A. Modro, J. Chem. Soc., Perkin Trans. 2, 1995, 2227 DOI: 10.1039/P29950002227
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