2-Ethoxy-3-methylidene-1,2λ5-oxaphospholan-2-one rings have been constructed by Pd(OAc)2–LiCl catalysed cyclization of 4-chlorobut-2-enyl ethyl alkynylphosphonate. A mechanism involving trans or cis halogenopalladation, followed by intramolecular insertion of a carbon–carbon double bond into a carbon–palladium bond and subsequent dehalogenopalladation, is briefly discussed.
C. Ma, X. Lu and Y. Ma, J. Chem. Soc., Perkin Trans. 1, 1995, 2683 DOI: 10.1039/P19950002683
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...