A range of α-alkoxyphosphonates, including novel α-methoxyallyl phosphonates have been prepared from acetals. The latter have been used to provide an efficient and convenient synthesis of conjugated methoxy dienes, in which E-geometry predominates in the newly formed double bond but the geometry of the original allyl system is preserved.
K. Fettes, L. McQuire and A. W. Murray, J. Chem. Soc., Perkin Trans. 1, 1995, 2123 DOI: 10.1039/P19950002123
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