The three isomeric bithienyls, 1, 2 and 3, formally related to the dimerization of 3-(methylsulfanyl)-thiophene, have been synthesized by the metal-catalysed coupling between a metallated and a halogenated derivative of thiophene of suitable structure. The 1H and 13C NMR data are discussed.
U. Folli, D. Iarossi, M. Montorsi, A. Mucci and L. Schenetti, J. Chem. Soc., Perkin Trans. 1, 1995, 537 DOI: 10.1039/P19950000537
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