Two experimentally simple steps [i, Me3GeH, H2PtCl6·6H2O (catalytic amount), CH2Cl2; ii, toluene-p-sulfonic acid monohydrate, CH2Cl2] serve to convert 1-trimethylsilylalk-1-ynes into synthetically useful 2-trimethylgermylalk-1-enes.
E. Piers and R. Lemieux, J. Chem. Soc., Perkin Trans. 1, 1995, 3 DOI: 10.1039/P19950000003
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