Laser-induced photolysis of the title silacycles in the gas phase is dominated by cleavage of the four-membered ring and results in deposition of polycarbosilanes formed by polymerization of assumed transient silenes and silylenes. The polycarbosilane films are reactive towards oxygen.
J. Pola, Z. Bastl, J. Šubrt and R. Taylor, J. Mater. Chem., 1995, 5, 1345 DOI: 10.1039/JM9950501345
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