Two dinuclear five-co-ordinated zinc complexes, derived from tris[(2-pyridyl)methyl] amine and bridged by a phosphate monoester or an inorganic phosphate group respectively, have been synthesized; the structures of the former has been established by X-Ray crystallography and shows the bridging mode of the phosphate to be syn–anti whereas in alkaline phosphatase it is syn–syn.
H. Adams, N. A. Bailey, D. E. Fenton and Q. He, J. Chem. Soc., Dalton Trans., 1995, 697 DOI: 10.1039/DT9950000697
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