Issue 2, 1995

Synthesis of [Au(NH3)2]+ salts and the crystal structure of [Au(NH3)2]Br

Abstract

The complexes [Au(NH2R)2]X (R = H, Me, Et or But; X = Br, SbF6 or BF4) have been synthesised and characterised by IR, NMR spectra and by thermal gravimetric and differential scanning calorimetry techniques; the single-crystal structural determination of [Au(NH3)2]Br has confirmed the linear co-ordination about gold and highlighted some interesting bond-length differences compared to [Ag(NH3)2]NO3.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 319-320

Synthesis of [Au(NH3)2]+ salts and the crystal structure of [Au(NH3)2]Br

D. M. P. Mingos, J. Yau, S. Menzer and D. J. Williams, J. Chem. Soc., Dalton Trans., 1995, 319 DOI: 10.1039/DT9950000319

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