W(PMe3)6 is an efficient chloride ion abstracting reagent for the synthesis of RP![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
PR species from RPCl2 precursors; moreover, the W(PMe3)6–RPCl2 solutions catalyse the exchange of the diphosphene PR end-groups via a mechanism closely related to the olefin metathesis process.
K. B. Dillon, V. C. Gibson and L. J. Sequeira, J. Chem. Soc., Chem. Commun., 1995, 2429 DOI: 10.1039/C39950002429
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