Isolation and structural determination of {(1,1,2,2-tetracyano-1,2-ethanediyl)bis[imino(cyanomethylene)]}bis(cyanamide) ion(2–), [C12N12]2–, a new cyanocarbon
Abstract
The oxidative degradation of [N(PPh3)2]3[MnIII(CN)6] leads to the isolation of the unprecedented [C12N12]2– dianion, which is characterized by single-crystal X-ray diffraction and spectroscopic techniques.
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