Issue 21, 1995

Synthesis and molecular structure of the first organometallic nitride cubane: [{Ti(η5-C5Me5)}43-N)4]

Abstract

The ammonolysis of [Ti(η5-C5Me5)(NMe2)3] at 90 °C affords the nitride complex [{Ti(η5-C5Me5)}43-N)4]; the X-ray crystal structure analysis shows a Ti4N4 core clearly similar to the structural motif of cubic titanium nitride.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2185-2186

Synthesis and molecular structure of the first organometallic nitride cubane: [{Ti(η5-C5Me5)}43-N)4]

P. Gómez-Sal, A. Martín, M. Mena and C. Yélamos, J. Chem. Soc., Chem. Commun., 1995, 2185 DOI: 10.1039/C39950002185

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