The Wittig rearrangement of 3-furylmethyl ethers 1, proceeds efficiently to give 3-methyl-2-furylmethanols 2 or 3-furylethanols 3 depending on the basicity of the butyllithium used; synthesis of dendrolasin is achieved with the 1,2-rearrangement of 3-furylmethyl geranyl ether 5 as a key step.
M. Tsubuki, H. Okita and T. Honda, J. Chem. Soc., Chem. Commun., 1995, 2135 DOI: 10.1039/C39950002135
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