Ester enolate Claisen rearrangement of chelated N-protected amino acid allylic esters results in the formation of α-alkylated γ,δ-unsaturated amino acids in good yields and in a highly diastereoselective fashion.
U. Kazmaier and S. Maier, J. Chem. Soc., Chem. Commun., 1995, 1991 DOI: 10.1039/C39950001991
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