Issue 18, 1995

Magnetic exchange coupling in a nearly linear iron(III)nickel(II)nickel(II)iron(III) complex

Abstract

The reaction of LFeIIICl3 with Ni2(Hdfmp)2(L = 1,4,7-trimethyl-1,4,7-triazacyclononane, H3dfmp = 2-hydroxy-5-methylbenzene-1,3-dicarbaldehyde dioxime) produces in the presence of triethylamine, acetate and tetrafluoroborate ions, the dark brown complex [L2Fe22-O2CMe)2(dfmp)2(MeOH)2Ni2](BF4)2 which is characterized by X-ray crystallography and magnetic susceptibility measurements and found to have a paramagnetic ground state.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1913-1915

Magnetic exchange coupling in a nearly linear iron(III)nickel(II)nickel(II)iron(III) complex

C. Krebs, M. Winter, T. Weyhermüller, E. Bill, K. Wieghardt and P. Chaudhuri, J. Chem. Soc., Chem. Commun., 1995, 1913 DOI: 10.1039/C39950001913

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