Crystals of (Aul)2{µ-bis(diphenylphosphino)hexane} form polymeric chains (through Au–Au contacts), which are interwoven to produce discrete layers that lie between cleavage planes of the crystal.
P. M. Van Calcar, M. M. Olmstead and A. L. Balch, J. Chem. Soc., Chem. Commun., 1995, 1773 DOI: 10.1039/C39950001773
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