The complexes [RuCl2(PPh3)(L)] in which L is a tridentate ligand with P, N and O donor atoms are very efficient catalysts for the transfer hydrogenation of cyclic ketones and acetophenone (turnover ⩽ 118 800 h–1) in basic media; when L is optically active, no significant e.e. is observed.
H. Yang, M. Alvarez, N. Lugan and R. Mathieu, J. Chem. Soc., Chem. Commun., 1995, 1721 DOI: 10.1039/C39950001721
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