The tetraphenylphosphonium salt of the hydrogen polyphosphide H2P7– is synthesized from K3P11 and PPh4Cl in liquid ammonia and the nortricyclene topology of the anion is proven by X-ray crystal structure analysis.
N. Korber and H. von Schnering, J. Chem. Soc., Chem. Commun., 1995, 1713 DOI: 10.1039/C39950001713
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