Issue 16, 1995

Preparation and ligating properties of the first example of a 1,2,4-triphosphole, P3C2But2R [R = CH(SiMe3)2]: crystal and molecular structures of P3C2But2CH(SiMe3)2, trans-[PtCl2(PEt3){P3But2CH(SiMe3)2}]and[Fe2(CO)6{µ-P3C2But2CH(sime3)2}]

Abstract

The first known triphosphole exhibits different modes of ligation to transition-metal centres.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1661-1662

Preparation and ligating properties of the first example of a 1,2,4-triphosphole, P3C2But2R [R = CH(SiMe3)2]: crystal and molecular structures of P3C2But2CH(SiMe3)2, trans-[PtCl2(PEt3){P3But2CH(SiMe3)2}]and[Fe2(CO)6{µ-P3C2But2CH(sime3)2}]

V. Caliman, P. B. Hitchcock and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1995, 1661 DOI: 10.1039/C39950001661

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