Issue 16, 1995

Cyclotrimerization of alkynes with [60]fullerene in the presence of tricyclohexylphosphine

Abstract

Treatment of [60]fullerene with HC[triple bond, length half m-dash]CCO2R in the presence of P(Cy)3 at ambient temperature affords a cyclotrimerization product (R = Et, 1; Me, 2) which results from a head-to-tail addition of two HC[triple bond, length half m-dash]CCO2R units to a 6–6 ring junction of [60]fullerene based on the observed spectral data.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1603-1604

Cyclotrimerization of alkynes with [60]fullerene in the presence of tricyclohexylphosphine

K. Liou and C. Cheng, J. Chem. Soc., Chem. Commun., 1995, 1603 DOI: 10.1039/C39950001603

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