Rhodium(I) carbonyl complexes containing phosphino-thiolate and -thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, [Rhl2(CO)2]–; the crystal structure of one procatalyst, [Rh(SC6H4PPh2)(CO)]2, is reported.
J. R. Dilworth, J. R. Miller, N. Wheatley, M. J. Baker and J. G. Sunley, J. Chem. Soc., Chem. Commun., 1995, 1579 DOI: 10.1039/C39950001579
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