Issue 15, 1995

The first examples of an aryl ring substituted by both phosphine and phosphonate moieties: synthesis and characterization of the new highly water-soluble phosphine ligand Na2[Ph2P(C6H4-p-PO3)]·1.5H2O and platinum(II) complexes

Abstract

The highly water-soluble phosphine Na2[TPPMP]·1.5H2O (TPPMP =‘triphenylphosphine monophosphonate’) represents the first example of a compound containing an aryl ring which is substituted by both phosphine and anionic phosphonate moieties; the preparation and spectroscopic characterisation of the platinum(II) complexes (trans-and cis-Na4[PtCl2(TPPMP)2]·3H2O is described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1487-1488

The first examples of an aryl ring substituted by both phosphine and phosphonate moieties: synthesis and characterization of the new highly water-soluble phosphine ligand Na2[Ph2P(C6H4-p-PO3)]·1.5H2O and platinum(II) complexes

T. L. Schull, J. C. Fettinger and D. A. Knight, J. Chem. Soc., Chem. Commun., 1995, 1487 DOI: 10.1039/C39950001487

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