New general syntheses, based on free-radical oxidative alkylation, acylation and arylation of acrylonitrile, in the presence of ButO2H, are reported; the concept of the peroxy group as a pseudohalide is suggested to explain these new reactions.
S. Araneo, F. Fontana, F. Minisci, F. Recupero and A. Serri, J. Chem. Soc., Chem. Commun., 1995, 1399 DOI: 10.1039/C39950001399
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