Treatment of TiCl4 with carboxylic acids RCO2H (R = C6F5, CH2C6F5, CH2OC6F5) yields a series of titanium oxo compounds; the X-ray molecular structure of [TiO(O2CC6F5)2] reveals an octameric unit and a unique 16-membered Ti8O8 ring, with two toluene molecules encapsulated above and below the ring in the molecular cavity.
H. Barrow, D. A. Brown, N. W. Alcock, H. J. Clase and M. G. H. Wallbridge, J. Chem. Soc., Chem. Commun., 1995, 1231 DOI: 10.1039/C39950001231
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