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Issue 12, 1995
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Unprecedented iridium catalysed group transfer reactions of 1,3-thiazanes

Abstract

Intramolecular allyl, benzyl or methylene ester transfer is observed upon treatment of suitably functionalized 1,3-thiazanes with catalytic amounts of either anhydrous iridium trichloride or chlorotricarbonyliridium in benzene under a carbon monoxide atmosphere (e.g. N-allyl-2-phenyl-1,3-thiazane is converted to N,S-diallyl-N-benzyl-1,3-aminothiol; the allyl unit is provided by a second molecule of the thiazane, which is in turn converted into the corresponding thiazine by formal loss of propene).

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Article information


J. Chem. Soc., Chem. Commun., 1995, 1199-1200
Article type
Paper

Unprecedented iridium catalysed group transfer reactions of 1,3-thiazanes

H. Alper, C. Crudden and K. Khumtaveeporn, J. Chem. Soc., Chem. Commun., 1995, 1199
DOI: 10.1039/C39950001199

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