A stable, chiral diaquo titanocene complex is an excellent catalyst for certain Diels–Alder reactions giving good enantioselectivity which indicates that catalysis occurs by metal rather than by proton activation of the dienophile.
W. Odenkirk and B. Bosnich, J. Chem. Soc., Chem. Commun., 1995, 1181 DOI: 10.1039/C39950001181
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