Both degradation and total synthesis from L-(+)-isoleucine are used to establish the absolute stereochemistry of the O-3′-acyl side chain of papulacandin D.
A. G. M. Barrett, M. Peña and J. A. Willardsen, J. Chem. Soc., Chem. Commun., 1995, 1145 DOI: 10.1039/C39950001145
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