(4R,5S)-trans-4,5-Bis(tert-butyldimethylsilyloxy)cyclopent-2-enone 8 and (4R,5S)-trans-4,5-di(benzyloxy)cyclopent-2-enone 20 are prepared by equilibration of the corresponding cis derivatives; enone 8 is transformed into the glucosidase inhibitor, D-1-deoxynojirimycin 14.
C. R. Johnson, B. M. Nerurkar, A. Golebiowski, H. Sundram and J. L. Esker, J. Chem. Soc., Chem. Commun., 1995, 1139 DOI: 10.1039/C39950001139
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