Palladium-catalysed coupling of p-tert-butylphenyl α-O-Δ2-glycopyranoside with various substituted arylmagnesium bromides provides the corresponding C-α-aryl-Δ2-glycopyranosides, while nickel-mediated reaction allows the preparation of the C-β-aryl anomers.
C. Moineau, V. Bolitt and D. Sinou, J. Chem. Soc., Chem. Commun., 1995, 1103 DOI: 10.1039/C39950001103
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