The fluorescence and chirality of photoswitchable inherently dissymmetric alkenes cis1 and trans-2-nitro-7-dimethylamino-9-(2′,3′-dihydro-1′H-naphtho[2,1-b]thiopyran-1′-ylidene)-9H-thioxanthene 2 are reversibly modulated by irradiation whereas photoresponsive effects and emission are regulated by reversible protonation.
N. P. M. Huck and B. L. Feringa, J. Chem. Soc., Chem. Commun., 1995, 1095 DOI: 10.1039/C39950001095
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