[K(18-crown-6)][(CO)4FePPh2]1 reacts with CS2 to produce the adduct [K(18-crown-6)][(CO)4FePPh2CS2]2 in high yield; an X-ray diffraction analysis confirms the phosphorus coordination of the PPh2CS2– ligand in 2 and shows weak contacts between the sulfur atoms and the potassium ion of the crown ether.
W. Petz and F. Weller, J. Chem. Soc., Chem. Commun., 1995, 1049 DOI: 10.1039/C39950001049
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