Ring opening of epoxides with trimethylsilyl azide is catalysed by ytterbium triisopropoxide at room temperature in THF, giving the corresponding vicinal azide alcohols in very high yields.
M. Meguro, N. Asao and Y. Yamamoto, J. Chem. Soc., Chem. Commun., 1995, 1021 DOI: 10.1039/C39950001021
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