Reaction of [PPh4]2[WS4] with ethyl bromide yields the tetraphenylphosphomum salt of the title anion 1, for which an X-ray structure determination reveals no evidence for an intramolecular redox reaction, but concentrated solutions undergo rapid reactions leading to [W3S9]2– and Et2Sx(x= 1–3).
P. M. Boorman, M. Wang and M. Parvez, J. Chem. Soc., Chem. Commun., 1995, 999 DOI: 10.1039/C39950000999
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