The rhodium(I) complex [Rh(cod)Cl]2 catalyses the selective insertion of carbon monoxide into the ring carbon–heteroatom bond of a side chain ether or thioether functional group of a tetrahydrothiophene or tetrahydrofuran.
K. Khumtaveeporn and H. Alper, J. Chem. Soc., Chem. Commun., 1995, 917 DOI: 10.1039/C39950000917
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