Issue 7, 1995

Mapping of the functional active site of Baeyer–Villigerases by substrate engineering

Abstract

An active site model for enzyme catalysed Baeyer–Villiger reactions is proposed and validated by transformation of the tricyclic ketone 6; Baeyer–Villiger reactions (and Baeyer–Villigerases) are classified by the stereochemistry of the hydroxyperoxide intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 729-730

Mapping of the functional active site of Baeyer–Villigerases by substrate engineering

D. R. Kelly, C. J. Knowles, J. G. Mahdi, I. N. Taylor and M. A. Wright, J. Chem. Soc., Chem. Commun., 1995, 729 DOI: 10.1039/C39950000729

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