Reaction of copper(I) ions with the oligobipyridine ligands 1 and the macrocycle 2 leads to the self-assembly of the di- and tri-nuclear rigid-rack complexes 3 of rotaxane type, whose nature has been confirmed by determination of the crystal structure of 3b.
H. Sleiman, P. Baxter, J. Lehn and K. Rissanen, J. Chem. Soc., Chem. Commun., 1995, 715 DOI: 10.1039/C39950000715
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