In the title reactions, unrearranged products (Me3Si)3C[Si(CD3)2Y] usually predominate over their rearranged isomers (Me3Si)2C[Si(CD3)2Me](SiMe2Y), revealing the inadequacy of the simplest mechanistic picture in which the two bridged silicon centres in a methyl-bridged cationic intermediate are equally available for attachment of a nucleophile.
A. I. Almansour, J. R. Black, C. Eaborn, P. M. Garrity and D. A. R. Happer, J. Chem. Soc., Chem. Commun., 1995, 705 DOI: 10.1039/C39950000705
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