Issue 5, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Organotitanium oxides as Lewis acidic supports of metal carbonyl species: [{Ti3(η5-C5Me5)3(µ-O)3Me}{(µ-OC)M(CO)2(η5-C5H5)}2](M = Mo, W)

Román Andrés,   Mijail Galakhov,   Avelino Martín,   Miguel Mena  and  Cristina Santamaría  

Abstract

Reaction of [{Ti(η5-C5Me5)(µ-O)}3(µ3-CH)]1 with [M(η5-C5H5)(CO)3H](M = Mo, W) leads to the formation of Lewis acid carbonyl adducts [{Ti3(η5-C5Me5)3(µ-O)3Me}{(µ-OC)M(CO)2(η5-C5H5)}2]4, 5 showing the transformation of the µ3-methylidyne group into a Me group through the µ-methylene intermediates [{Ti3(η5-C5Me5)3(µ-O)3(µ-CH2)}(µ-OC)M(CO)2(η5-C5H5)]2, 3.

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Article information

DOI
https://doi.org/10.1039/C39950000551
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 551-552

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Organotitanium oxides as Lewis acidic supports of metal carbonyl species: [{Ti3(η5-C5Me5)3(µ-O)3Me}{(µ-OC)M(CO)2(η5-C5H5)}2](M = Mo, W)

R. Andrés, M. Galakhov, A. Martín, M. Mena and C. Santamaría, J. Chem. Soc., Chem. Commun., 1995, 551 DOI: 10.1039/C39950000551

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